| 有机锡化合物四对氰苄基锡(p-NCC6H4CH2)4Sn的合成、表征和晶体结构 |
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| 引用本文： | 尹汉东,高中军,徐浩龙,李刚. 有机锡化合物四对氰苄基锡(p-NCC6H4CH2)4Sn的合成、表征和晶体结构[J]. 无机化学学报, 2005, 21(11): 1743-1746 |
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| 作者姓名： | 尹汉东 高中军 徐浩龙 李刚 |
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| 作者单位： | 聊城大学化学化工学院,聊城,252059 |
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| 基金项目： | 国家自然科学基金(No.20271025)，山东省自然科学基金(No.L2003B01)资助课题。 |
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| 摘 要： | The organotin(Ⅳ) compound (p-NCC6H4CH2)4Sn was synthesized by the reaction of p-cyanobenzyl chloride with tin. The compound was characterized by elemental analysis, IR, 1H NMR, and the crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to triclinic, space group P1 with a=0.894 1(4) nm, b=0.977 9(4) nm, c=1.796 8(8) nm, V=1.386 9(11) nm3, Z=2, Dc=1.397 Mg·m-3, μ(Mo Kα)=0.948 mm-1, F(000)=588, R1=0.046 9, wR2=0.101 4. The tin atom adopts a distorted tetrahedral coordination geometry. CCDC: 272939.
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| 关 键 词： | 四对氰苄基锡； 合成； 晶体结构 |
| 文章编号： | 1001-4861(2005)11-1743-04 |
| 收稿时间： | 2005-04-18 |
| 修稿时间： | 2005-08-11 |
Synthesis, Characterization and Crystal Structures of the Organotin(Ⅳ) Compound Tetra(p-Cyanobenzyl)tin (p-NCC6H4CH2)4Sn |
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| YIN Han-Dong,GAO Zhong-Jun,XU Hao-Long and LI Gang. Synthesis, Characterization and Crystal Structures of the Organotin(Ⅳ) Compound Tetra(p-Cyanobenzyl)tin (p-NCC6H4CH2)4Sn[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(11): 1743-1746 |
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| Authors: | YIN Han-Dong GAO Zhong-Jun XU Hao-Long LI Gang |
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| Affiliation: | Department of Chemistry, Liaocheng University, Liaocheng 252059,Department of Chemistry, Liaocheng University, Liaocheng 252059,Department of Chemistry, Liaocheng University, Liaocheng 252059 and Department of Chemistry, Liaocheng University, Liaocheng 252059 |
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| Abstract: | |
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| Keywords: | tetra(4-cyanobenzyl)tin synthesis crystal structure |
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