| 手性季铵盐类相转移催化剂的新进展 |
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| 引用本文： | 沈宗旋,孔爱娣,陈文勇,张雅文. 手性季铵盐类相转移催化剂的新进展[J]. 有机化学, 2003, 23(1): 10-21 |
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| 作者姓名： | 沈宗旋 孔爱娣 陈文勇 张雅文 |
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| 作者单位： | 苏州大学化学化工系,苏州,215006 |
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| 基金项目： | 江苏省教育厅自然科学基金 (No.0 1KJB1 50 0 0 2 )资助项目 |
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| 摘 要： | 叙述了手性季铵盐类相转移催化剂在不对称催化反应（包括活性亚甲基的烷基 化、Michael加成、双键的环氧化、Darzens缩合、氮杂环丙烷的合成、羟醛缩合以 及Horner-Wadsworth-Emmons反应）中应用的新进展。
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| 关 键 词： | 相转移催化 不对称 催化反应 活性 甲基 烷基化 迈克尔加成反应 |
Recent Advances in Chiral Quaternary Ammonium Salts as Phase- Transfer Catalysts |
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| SHEN,Zong-Xuan KONG,Ai-Di CHEN,Wen-Yong ZHANG,Ya-Wen. Recent Advances in Chiral Quaternary Ammonium Salts as Phase- Transfer Catalysts[J]. Chinese Journal of Organic Chemistry, 2003, 23(1): 10-21 |
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| Authors: | SHEN Zong-Xuan KONG Ai-Di CHEN Wen-Yong ZHANG Ya-Wen |
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| Affiliation: | Department of Chemistry and Chemical Engineering,Suzhou University, Suzhou(215006) |
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| Abstract: | This article reviews the recent advances in the application of chiral quaternary ammonium salts as phase-transfer catalysts in asymmetric catalytic reactions, including the alkylation of active methylene group, the Michael addition reaction, the epoxidation of chalcones, the Darzens condensation, the synthesis of azacyclopropanes, the aldol condensation and the Horner-Wadsworth-Emmons reaction. |
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| Keywords: | chiral quaternary ammonium salt phase-transfer catalyst asymmetric catalytic reaction recent advance |
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