Highly Sensitive and Selective Chemosensor for Cu2+ Based on a Schiff Base |
| |
Authors: | ,
CAO Ben-nan
,
HU Qin
,
HUANG Yan
,
JIA Chun-man
,
ZHANG Qi |
| |
Institution: | 1. Key Study Center of Ministry of Education for Tropical Resources Utilization, Hainan Provincial Key Lab of Fine Chemicals, Hainan University, Haikou 570228, P. R. China;
2. Department of Chemistry and Chemical Engineering, Jiangsu University, Jiangsu 212013, P. R. China |
| |
Abstract: | A new chemosensor based on a Schiff base has been designed and synthesized. Its sensing behavior toward various metal ions was investigated by fluorescence and UV-Vis spectroscopic methods. The fluorescence of the sensor was quenched and the color rapidly changed from canary yellow to brown after the addition of Cu2+, while no changes occurred after the addition of other metal ions, which contributes to the detection of Cu2+ with naked eyes. The fluorescence quantum yield of the ligand was calculated to be 0.52. The corresponding detection limit of Cu2+ was 5.721×10-7 mol/L, and the 1:1 binding mode of the sensor with Cu2+ was revealed by Job's plot. |
| |
Keywords: | Chemosensor Schiff base Copper ion Naked-eye detection Quench |
本文献已被 万方数据 等数据库收录! |
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |
|