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Fe2O3掺杂TiO2催化超声降解甲基橙溶液的研究
引用本文:王君,韩建涛,赵迪,张向东,李绮,李莹.Fe2O3掺杂TiO2催化超声降解甲基橙溶液的研究[J].应用基础与工程科学学报,2003,11(4):345-351.
作者姓名:王君  韩建涛  赵迪  张向东  李绮  李莹
作者单位:1. 辽宁大学化学系,辽宁,沈阳,110036
2. 辽宁大学环境科学系,辽宁,沈阳,110036
3. 辽宁大学分析测试中心,辽宁,沈阳,110036
基金项目:国家自然科学基金(批准号:20371023)资助项目
摘    要:采用实验室合成的Fe2O3掺杂TiO2作为催化剂,以甲基橙超声降解反应为模型,研究了各种因素对Fe2O3掺杂TiO2催化超声降解甲基橙的影响,研究表明在Fe2O3掺杂TiO2催化剂作用下超声降解甲基橙的效果非常明显,催化剂用量在0.3-0.5g/L之间,超声波频率25kHz,输出功率1.0W/cm^2,pH为1.0时,甲基橙水溶液初始浓度为20mg/L的条件下,90min左右基本可全部降解,COD的去除率也达到了99.0%,因此,Fe2O3掺杂TiO2催化超声降解有机污染物的方法具有很好的应用前景。

关 键 词:印染工业  废水处理  氧化铁  掺杂  二氧化钛  超声降解  甲基橙溶液  催化
文章编号:1005-0930(2003)-04-0345-07
修稿时间:2003年8月28日

A Study on Ultrasonic Degradation of Methyl Orange in the Presences of Fe2O3 Doping TiO2 Catalyst
WANG Jun,HAN Jiantao,ZHAO Di,ZHANG Xiangdong,LI Qi,LI Ying.A Study on Ultrasonic Degradation of Methyl Orange in the Presences of Fe2O3 Doping TiO2 Catalyst[J].Journal of Basic Science and Engineering,2003,11(4):345-351.
Authors:WANG Jun  HAN Jiantao  ZHAO Di  ZHANG Xiangdong  LI Qi  LI Ying
Institution:WANG Jun~1,HAN Jiantao~1,ZHAO Di~2,ZHANG Xiangdong~1,LI Qi~3,LI Ying~3
Abstract:The various affecting factors were studied on ultrasonic degradation of methyl orange in the presence of Fe_2O_3 doping TiO_2 catalyst prepared in laboratory in this paper. The researched results indicate the effects of ultrasonic degradation are more obvious in the presence of Fe_2O_3 doping TiO_2 catalyst than in absent of catalyst, and also than in the presence of sold anatase and rutile TiO_2 catalysts in the acidic condition (pH=1.0) irradiated with the ultrasound of 25kHz frequency and (1.0W/cm~2) power input about 90 min and the degradation rate of methyl orange and its elimination rate of COD can get to 100% and 99.0%, respectively. Thereby the ultrasonic degradation of organic pollutants catalyzed by Fe_2O_3 doping TiO_2 catalyst are better useful prospect.
Keywords:methyl orange  ultrasonic degradation  Fe_2O_3 doping TiO_2
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