Specific MARY spectrum from radical anion of pentafluorobenzene |
| |
| Authors: | E. V. Kalneus A. A. Kipriyanov P. A. Purtov D. V. Stass Yu. N. Molin |
| |
| Affiliation: | 1. Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Institutskaya ulitsa 3, 630090, Novosibirsk, Russian Federation
2. Novosibirsk State University, Novosibirsk, Russian Federation
|
| |
| Abstract: | The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
