| 一维链状配位聚合物[Cu3(TFSSB)2·(H2O)4·4H2O]n的合成和晶体结构 |
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| 引用本文： | 刘志敏,蒋毅民,蔡金华. 一维链状配位聚合物[Cu3(TFSSB)2·(H2O)4·4H2O]n的合成和晶体结构[J]. 无机化学学报, 2005, 21(5): 733-735 |
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| 作者姓名： | 刘志敏 蒋毅民 蔡金华 |
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| 作者单位： | 广西师范大学化学化工学院,桂林,541004 |
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| 基金项目： | 广西自然科学基金(No.0339034)，广西高校科研基金资助项目。 |
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| 摘 要： | The title complex [Cu3(TFSSB)2·(H2O)4·4H2O]n (TFSSB=taurine 3-formylsalicylic schiff base) was synthesized by TFSSB and copper(Ⅱ) acetate monohydrate in ethanol solution and the crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic system, space group P21 / n，with cell parameters: a=0.927 9(6) nm, b=1.173 0(2) nm, c=1.471(2) nm, β=106.96(2)°, and V=1.531(2) nm3, Z=2, Dc=1.890 g·cm-3, μ=2.291 mm-1, F(000)=882, R1=0.025 9, wR2=0.065 9. The Cu1 is five-coordinate, the Cu2 is four-coordinate. CCDC: 253298.
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| 关 键 词： | 配位聚合物； 晶体结构； 牛磺酸缩-3-醛基水杨酸席夫碱 |
| 文章编号： | 1001-4861(2005)05-0733-03 |
| 收稿时间： | 2004-09-06 |
| 修稿时间： | 2004-09-06 |
Synthesis and Crystal Structure of Coordination Polymer [Cu3(TFSSB)2· (H2O)4· 4H2O]n with 1D Chain |
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| LIU Zhi-Min,JIANG Yi-Min and CAI Jin-Hua. Synthesis and Crystal Structure of Coordination Polymer [Cu3(TFSSB)2· (H2O)4· 4H2O]n with 1D Chain[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(5): 733-735 |
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| Authors: | LIU Zhi-Min JIANG Yi-Min CAI Jin-Hua |
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| Affiliation: | College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 and College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 |
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| Abstract: | |
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| Keywords: | coordination polymer crystal structure taurine 3-formylsalicylic schiff base |
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