Synthesis and Crystal Structure of 2,10-Di-tert-butylindolo[3,2,1-jk]carbazole |
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Authors: | LV Jun LIU Qian-Cai TANG Jie |
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Institution: | Department of Chemistry, East China Normal University, Shanghai 200062, China |
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Abstract: | The title compound, 2,10-di-tert-butylindolo3,2,1-jk]carbazole (C26H27N, Mr=353.49), has been synthesized by palladium-catalyzed intramolecular arylation and characterized by 1H NMR, 13C NMR and X-ray crystal structure determination. The crystal crystallizes in the monoclinic system, space group P21/c with a=13.6409(5), b=11.6706(4), c=13.1678(5), β=100.6180(10)°, V=2060.39(13)3 , Z=4, Dc=1.140 mg/m3 , μ=0.065mm-1 , F(000)=760, the final R=0.0456 and wR=0.1209 for 3012 observed reflections (I > 2σ(I)). |
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Keywords: | indolo[3 2 1-jk]carbazole palladium intramoleculararylation synthesis crystal structure |
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