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| Synthesis and Crystal Structure of 2-(4-Nitrophenyl)-1,2-benzisoselenazol-3(2H)-one DMF (1:1) Solvate | |
| 引用本文： | LI Hao-Yang,HAN Hong-Fei,LI Wen-Juan,WEI Xue-Hong. Synthesis and Crystal Structure of 2-(4-Nitrophenyl)-1,2-benzisoselenazol-3(2H)-one DMF (1:1) Solvate[J]. 结构化学, 2012, 31(6): 910-914 |
| 作者姓名： | LI Hao-Yang HAN Hong-Fei LI Wen-Juan WEI Xue-Hong |
| 作者单位： | [1]Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China [2]Institute of Applied Chemistr）; Shanxi University, Taiyuan 030006, China |
| 基金项目： | This work was carried out under the sponsorship of the project of Shanxi Scientific Technology （No. 20110321044） |
| 摘 要： | The title compound (C13H8N2O3Se-C3H7NO) has been synthesized by a simple synthetic route and by recrystallization from DMF. The molecular structure of this compound was obtained by single-crystal X-ray diffraction. The compound crystallized in the triclinic space group P with a = 7.450(6), b = 8.150(7), c = 13.859(12) , α = 75.014(14), β = 83.072(18), γ = 84.409(14)°, V = 805.0(12)3, Z = 2 and R = 0.0271 for 2575 observed reflections with I > 2σ(I). X-ray analysis reveals that not only intermolecular Se…O and C-H…O interactions, but also π…π stacking interactions exist in the adjacent molecules. The above three kinds of intermolecular interactions extend the complex into an infinite three-dimensional layered network. |
| 关 键 词： | synthesis crystal structure intermolecular interaction |
Synthesis and Crystal Structure of 2-（4-Nitrophenyl）- 1,2-benzisoselenazol-3（2H）-one DMF （1：1） Solvate |
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| LI Hao-Yanga HAN Hong-Feia, b LI Wen-Juana WEI Xue-Hong. Synthesis and Crystal Structure of 2-（4-Nitrophenyl）- 1,2-benzisoselenazol-3（2H）-one DMF （1：1） Solvate[J]. Chinese Journal of Structural Chemistry, 2012, 31(6): 910-914 | |
| Authors: | LI Hao-Yanga HAN Hong-Feia b LI Wen-Juana WEI Xue-Hong |
| Affiliation: | 1. Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China 2. Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China／Institute of Applied Chemistr）; Shanxi University, Taiyuan 030006, China 3. Institute of Applied Chemistr）; Shanxi University, Taiyuan 030006, China |
| Abstract: | The title compound (C13H8N2O3Se-C3H7NO) has been synthesized by a simple synthetic route and by recrystallization from DMF. The molecular structure of this compound was obtained by single-crystal X-ray diffraction. The compound crystallized in the triclinic space group P with a = 7.450(6), b = 8.150(7), c = 13.859(12) , α = 75.014(14), β = 83.072(18), γ = 84.409(14)°, V = 805.0(12)3, Z = 2 and R = 0.0271 for 2575 observed reflections with I > 2σ(I). X-ray analysis reveals that not only intermolecular Se…O and C-H…O interactions, but also π…π stacking interactions exist in the adjacent molecules. The above three kinds of intermolecular interactions extend the complex into an infinite three-dimensional layered network. |
| Keywords: | synthesis crystal structure intermolecular interaction |
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