| 无溶剂体系中酶法合成2-辛基十二烷醇酯 |
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| 引用本文： | 安庆大,周玉俐,陈海昌. 无溶剂体系中酶法合成2-辛基十二烷醇酯[J]. 合成化学, 2000, 8(4): 287-290 |
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| 作者姓名： | 安庆大 周玉俐 陈海昌 |
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| 作者单位： | 1. 大连轻工业学院化学工程系,大连,116034
2. 大连轻工业学院食品科学与工程系,大连,116001 |
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| 摘 要： | 考察了无溶剂反应体系下脂脂酶催化直接酯化合成２－辛基十二烷醇酯。在ｍｏｌ醇：ｍｏｌ酸＝１．６：１，反应温度６０℃，脂肪酶添加量４％，反应时间１０ｈ的最佳条件下，酯化率可达９４．８％。
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| 关 键 词： | 酯化反应 脂肪酶 2－辛基十二烷醇酯 酶法合成 |
Lipase-catalyzed Synthesis of 2-Octanyl-dodecanol Stearicate by Direct Esterification in a Solvent-free Medium |
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| Abstract. Lipase-catalyzed Synthesis of 2-Octanyl-dodecanol Stearicate by Direct Esterification in a Solvent-free Medium[J]. Chinese Journal of Synthetic Chemistry, 2000, 8(4): 287-290 |
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| Authors: | Abstract |
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| Abstract: | The synthesis of 2-octanyl-dodecanol stearicate from stearic acid and Guerbet alcohol was investigated in a solvent-free medium by lipase catalysis. The optimum reaction conditions were established as follows: molalcohol : molacid＝ 1. 6 : 1, temperature 60°C, amount of lipase 4%, reaction time 10h. The highest conversion reached 94.8%. |
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| Keywords: | Stearic acid Guerbet alcohol Esterification Lipase Biocatalyst. |
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