Study of the solid solution of MoO3 in Fe2V4O13 |
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Authors: | J Walczak M Kurzawa |
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Institution: | (1) Institute of Fundamental Chemistry, Polytechnical University of Szczecin, Al. Piastów 42, 71-065 Szczecin, Poland |
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Abstract: | Differential thermal and phase X-ray analyses have shown that MoO3 and Fe2V4O13 form a solid substitution solution, in which Mo6+ ions are incorporate into the crystal lattice of Fe2V4O13 in place of V5+ ions. The solubility limit of MoO3 in Fe2V4O13 at ambient temperature is 18 mole % of MoO3. The phase equilibria in the system Fe2V4O13-FeVMoO7, were also studied. Results are presented in the form of a phase diagram.
Zusammenfassung Durch DTA und Röntgenphasenanalyse wurde gezeigt, daß MoO3 und Fe2V4O13 Substitutionsmischkristalle bilden, in denen Mo6+-Ionen anstelle von V5+-Ionen in das Kristallgitter von Fe2V4O13 eingebaut sind. Die Löslichkeitsgrenze von MoO3 in Fe2V4O13 beträgt bei Umgebungstemperatur 18 Mol-% MoO3. Ebenfalls wurden die Phasengleichgewichte im System Fe2V4O13-FeVMoO7 untersucht. Die Ergebnisse sind in Form eines Phasendiagramms dargestellt.
![Rcy](/content/x5q7251u34383342/xxlarge1056.gif) ![iecy](/content/x5q7251u34383342/xxlarge1077.gif) ![zcy](/content/x5q7251u34383342/xxlarge1079.gif) ![yucy](/content/x5q7251u34383342/xxlarge1102.gif) ![mcy](/content/x5q7251u34383342/xxlarge1084.gif) ![Dcy](/content/x5q7251u34383342/xxlarge1044.gif) ![icy](/content/x5q7251u34383342/xxlarge1080.gif) ![fcy](/content/x5q7251u34383342/xxlarge1092.gif) ![fcy](/content/x5q7251u34383342/xxlarge1092.gif) ![iecy](/content/x5q7251u34383342/xxlarge1077.gif) ![rcy](/content/x5q7251u34383342/xxlarge1088.gif) ![iecy](/content/x5q7251u34383342/xxlarge1077.gif) ![ncy](/content/x5q7251u34383342/xxlarge1085.gif) ![tscy](/content/x5q7251u34383342/xxlarge1094.gif) ![icy](/content/x5q7251u34383342/xxlarge1080.gif) ![acy](/content/x5q7251u34383342/xxlarge1072.gif) ![lcy](/content/x5q7251u34383342/xxlarge1083.gif) ![softcy](/content/x5q7251u34383342/xxlarge1100.gif) ![ncy](/content/x5q7251u34383342/xxlarge1085.gif) 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![ycy](/content/x5q7251u34383342/xxlarge1099.gif) %. ![Icy](/content/x5q7251u34383342/xxlarge1048.gif) ![zcy](/content/x5q7251u34383342/xxlarge1079.gif) ![ucy](/content/x5q7251u34383342/xxlarge1091.gif) ![chcy](/content/x5q7251u34383342/xxlarge1095.gif) ![iecy](/content/x5q7251u34383342/xxlarge1077.gif) ![ncy](/content/x5q7251u34383342/xxlarge1085.gif) ![tcy](/content/x5q7251u34383342/xxlarge1090.gif) ![acy](/content/x5q7251u34383342/xxlarge1072.gif) ![kcy](/content/x5q7251u34383342/xxlarge1082.gif) ![zhcy](/content/x5q7251u34383342/xxlarge1078.gif) ![fcy](/content/x5q7251u34383342/xxlarge1092.gif) ![acy](/content/x5q7251u34383342/xxlarge1072.gif) ![zcy](/content/x5q7251u34383342/xxlarge1079.gif) ![ocy](/content/x5q7251u34383342/xxlarge1086.gif) ![vcy](/content/x5q7251u34383342/xxlarge1074.gif) ![ocy](/content/x5q7251u34383342/xxlarge1086.gif) ![rcy](/content/x5q7251u34383342/xxlarge1088.gif) ![acy](/content/x5q7251u34383342/xxlarge1072.gif) 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