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Insertion of chloral into P-Br bond of phosphoranes |
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| Authors: | V. F. Mironov T. N. Sinyashina E. N. Ofitserov P. P. Chernov I. V. Konovalova A. N. Pudovik |
| Affiliation: | (1) V. I. Ulyanova-Lenin State University, Kazan |
| Abstract: | Chloral inserts into the P-Br bond of pyrocatechintribromophosphorane with the formation of stable mono-, di- and tri(1-bromo-2,2,2-trichloroethoxy) phosphoranes and, also, into the P-Br bond of bis (pyrocatechin) bromophosphorane with the formation of 1-bromo-2,2,2-trichloroethoxybis (pyrocatechin) phosphorane.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2819–2823, December, 1989. |
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