| 喹啉氧基乙酰胺的Li(I)/Na(I)配合物及其高氯酸盐的结构和荧光性质 |
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| 引用本文： | 毛盼东,吴伟娜,杨苗,杨庆雯,王元. 喹啉氧基乙酰胺的Li(I)/Na(I)配合物及其高氯酸盐的结构和荧光性质[J]. 无机化学学报, 2013, 29(18) |
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| 作者姓名： | 毛盼东 吴伟娜 杨苗 杨庆雯 王元 |
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| 作者单位： | 河南理工大学化学化工学院, 焦作 454000,河南理工大学化学化工学院, 焦作 454000,河南理工大学化学化工学院, 焦作 454000,河南理工大学化学化工学院, 焦作 454000,河南理工大学化学化工学院, 焦作 454000 |
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| 基金项目： | 国家自然科学基金（No.21001040）、河南省科技厅基础与前沿项目（No.162300410011）和河南省青年骨干教师项目（No.2014GGJS-045）资助。 |
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| 摘 要： | 合成并通过X射线单晶衍射表征了配合物[Li（L）2]ClO4（1）和[Na（L）2]ClO4（2）的结构（L为2-（5-氯-喹啉-8-基氧基）1-吡咯烷酮）。单晶衍射结果表明，配合物1与2同构，金属离子与来自2个酰胺配体L的N2O4电子供体配位，形成扭曲的八面体配位构型。此外，还测定了配体高氯酸盐（HL）ClO4·H2O的结构，并详细研究了3个化合物的荧光性质。
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| 关 键 词： | 主族金属配合物 酰胺型配体 喹啉 晶体结构 荧光 |
| 收稿时间： | 2017-09-11 |
| 修稿时间： | 2017-12-28 |
Li(I)/Na(I) Complexes and Perchlorate Salt of 2-(5-Chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone: Syntheses, Crystal Structures and Fluorescence Properties |
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| MAO Pan-Dong,WU Wei-N,YANG Miao,YANG Qing-Wen and WANG Yuan. Li(I)/Na(I) Complexes and Perchlorate Salt of 2-(5-Chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone: Syntheses, Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(18) |
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| Authors: | MAO Pan-Dong WU Wei-N YANG Miao YANG Qing-Wen WANG Yuan |
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| Affiliation: | College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China,College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China,College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China,College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China and College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China |
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| Abstract: | Two complexes,[Li(L)2]ClO4 (1) and[Na(L)2]ClO4 (2) based on L (L=2-(5-chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone) were synthesized and characterized by the X-ray diffraction analyses. The results show that complex 1 was isostructural with 2. The metal ion in each complex with a distorted octahedron geometry is surrounded by two acetamide ligands with N2O4 donor set. In addition, the structure of the perchlorate salt of L, namely (HL)ClO4·H2O was demonstrated. The fluorescence properties of all compounds have been investigated in detail. |
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| Keywords: | main-group metal complexes amide type ligand quinoline crystal structure fluorescence |
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