| 固相配位化学反应研究——ⅩⅩⅩⅤ 热分解合成Co-N2配合物及其加氢性质研究 |
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| 引用本文： | 忻飞波,郑丽敏,忻新泉.固相配位化学反应研究——ⅩⅩⅩⅤ 热分解合成Co-N2配合物及其加氢性质研究[J].无机化学学报,1992,8(1):82-84. |
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| 作者姓名： | 忻飞波 郑丽敏 忻新泉 |
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| 作者单位： | 南京大学配位化学研究所, 南京 210008,南京大学配位化学研究所, 南京 210008,南京大学配位化学研究所, 南京 210008 |
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| 摘 要： | This paper reports the thermodecomposition of K3Co(CN)5N3]·2H2O both in helium and hydrogen atmosphere with gas chromatography. The product in helium at 250℃ have been studied by IR, Raman, ESR and XRD. The dinitrogen complexes of K3Co(CN)5N2 and K6Co2(CN)10N2] have been identified, and those dinitrogen complexes could be hydrogenized under hydrogen atmosphere to obtain ammonia.
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| 关 键 词： | 钴配合物 热分解 分子氮配体 |
| 收稿时间： | 1989/10/14 0:00:00 |
STUDIES ON SOLID STATE REACTION OF COORDINATION COMPOUNDS XXXV. SYNTHESIS AND HYDROGENATION OF COBALT -DINITROGEN COMPLEX BY THERMODECOMPOSITION REACTION |
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| Xin Feibo,Zheng Liming and Xin Xinquan.STUDIES ON SOLID STATE REACTION OF COORDINATION COMPOUNDS XXXV. SYNTHESIS AND HYDROGENATION OF COBALT -DINITROGEN COMPLEX BY THERMODECOMPOSITION REACTION[J].Chinese Journal of Inorganic Chemistry,1992,8(1):82-84. |
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| Authors: | Xin Feibo Zheng Liming and Xin Xinquan |
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| Institution: | Coordination Chemistry Institute. Nanjing University, Nanjing 210008,Coordination Chemistry Institute. Nanjing University, Nanjing 210008 and Coordination Chemistry Institute. Nanjing University, Nanjing 210008 |
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| Abstract: | |
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| Keywords: | thermodecomposition dinitrogen complex |
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