| N-水杨酰基二茂铁乙酮腙金属(Ⅱ)配合物的合成及表征 |
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| 引用本文： | 张洪云,陈东立,王松波,车得基,陈建勋.N-水杨酰基二茂铁乙酮腙金属(Ⅱ)配合物的合成及表征[J].无机化学学报,1992,8(2):222-224. |
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| 作者姓名： | 张洪云 陈东立 王松波 车得基 陈建勋 |
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| 作者单位： | 郑州大学化学系，郑州大学化学系，郑州大学化学系，郑州大学化学系，郑州大学化学系 郑州 450052，郑州 450052，郑州 450052，郑州 450052，郑州 450052 |
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| 摘 要： | 二茂铁芳酰腙具有较强的生理活性,能与细胞中的过渡金属离子形成稳定的配合物,抑制许多酶催化反应。它与金属离子容易形成深色配合物,常用于分析化学和金属离子萃取剂。水杨酰基二茂铁乙酮腙的甲酰基邻位存在一个有配位能力的酚基,有可能产生新形式配位,Patil和Hundekar已分别报道了水杨酰基二茂铁乙酮腙的一些过渡金属配合物。本文合成了该配体的Zn(Ⅱ)、Cd(Ⅱ)和Pb(Ⅱ)的配合物,用元素分析、IR光谱、UV光谱、TG-DTA和NMR谱进行了表征。
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| 关 键 词： | 二茂铁乙酮腙 配合物 N－水杨酰基 |
| 收稿时间： | 1990/7/21 0:00:00 |
SYNTHESES AND CHARACTERIZATION OF METAL (II) COORDINATION COMPOUND OF N-SALICYLOYL ACETOFERROCENYL HYDRAZONE |
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| Zhang Hongyun,Chen Dongli,Wang Songbo,Che Deji and Chen Jianxun.SYNTHESES AND CHARACTERIZATION OF METAL (II) COORDINATION COMPOUND OF N-SALICYLOYL ACETOFERROCENYL HYDRAZONE[J].Chinese Journal of Inorganic Chemistry,1992,8(2):222-224. |
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| Authors: | Zhang Hongyun Chen Dongli Wang Songbo Che Deji and Chen Jianxun |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | Several new coordination compound of N-salicyloyl acetoferronyl hydrazone with metal ions Zn(II), Cd(II) and Pb(II) are synthesized for the first time and characterized by their elemental analysis, IR, UV, H1 NMR spectral and TG-DTA studies. The ligand coordinates these metals through azomethine nitrogen and amide oxygen in enol form. The coordination compound are much more thermostable than the ligand because of forming the chelate ring. |
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| Keywords: | salicyloyl hydrazine acetyferrocene acetoferrocenyl hydrazone coordination compound |
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