| 吡唑-3,5-二(N-烷基甲酰胺)类配体的双核铜配合物的合成和结构 |
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| 引用本文： | 傅德刚,王国雄,曾成. 吡唑-3,5-二(N-烷基甲酰胺)类配体的双核铜配合物的合成和结构[J]. 无机化学学报, 1992, 8(3): 250-254 |
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| 作者姓名： | 傅德刚 王国雄 曾成 |
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| 作者单位： | 南京大学, 配位化学研究所, 南京 210008,南京大学, 配位化学研究所, 南京 210008,南京大学, 配位化学研究所, 南京 210008 |
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| 摘 要： | 合成了吡唑-3,5-二(N-烷基甲酰胺)(LH3)的一系列配合物:(LH2)2Cu2(NO3)2·H2O,L2Cu2Na2·nH2O。得到了(PEAH2)2Cu2(NO3)
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| 关 键 词： | 吡唑 酰胺 双核铜配合物 自旋交换 |
| 收稿时间： | 1990-10-19 |
SYNTHESIS AND STRUCTURE OF DICOPPER COMPLEXES OF PYRAZOLE-3,5-BIS(N-ALKYLCARBOXY AMIDE) |
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| Fu Degang,Wang Guoxiong and Zeng Cheng. SYNTHESIS AND STRUCTURE OF DICOPPER COMPLEXES OF PYRAZOLE-3,5-BIS(N-ALKYLCARBOXY AMIDE)[J]. Chinese Journal of Inorganic Chemistry, 1992, 8(3): 250-254 |
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| Authors: | Fu Degang Wang Guoxiong Zeng Cheng |
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| Affiliation: | Coordination Chemistry Institute, Nanjing University, Nanjing 210008,Coordination Chemistry Institute, Nanjing University, Nanjing 210008 and Coordination Chemistry Institute, Nanjing University, Nanjing 210008 |
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| Abstract: | We have synthesized a number of new complexes (LH2)2Cu2(NO3)2·H2O,L2Cu2Na2·nH2O, where LH3 = Pyrazolc-3,5-bis(N-a1kylcarboxyamide). From elemental analysis data and IR spectra, we suggest the formation of neutral amide complexes in neutral solution and the deprotonated amide complexes in high pH solution. The crystal structure of (PEAH2)2Cu2(NO3)2·H2O, where PEAH3 = Pyrazole-3,5-bis(N-ethylcarboxyamide), was obtained by X-ray single crystal analysis. The ESR spectra of complexes show that there arc spin-exchange interaction between two copper atoms in the molecules. |
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| Keywords: | pyrazole carboxyamide dinuclear copper complex spin-exchange |
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