| Na4Sn9与一些配合物相互作用的119Sn和23Na NMR研究 |
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| 引用本文： | 汪信,杨绪杰,陆路德,宋启泽,王文哲,顾蔚红. Na4Sn9与一些配合物相互作用的119Sn和23Na NMR研究[J]. 无机化学学报, 1992, 8(1): 62-64 |
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| 作者姓名： | 汪信 杨绪杰 陆路德 宋启泽 王文哲 顾蔚红 |
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| 作者单位： | 华东工学院近代化学研究室, 南京 210014,华东工学院近代化学研究室, 南京 210014,华东工学院近代化学研究室, 南京 210014,华东工学院近代化学研究室, 南京 210014,华东工学院近代化学研究室, 南京 210014,华东工学院近代化学研究室, 南京 210014 |
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| 摘 要： | 以199Sn和23Na核磁共振研究了Na4Sn9-乙二胺体系中加入M(acacen)(M=Cu2+,Ni2+)和Ln(fod)3(Ln=Pr3+,Yb3+,Eu3+)后的化学位移和偶合常数。结果表明,假接触和体积磁化率的变化是引起化学位移变化的主要原因,而Fermi接触的贡献可以忽略。
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| 关 键 词： | Zintl离子 络合物 假接触 锡化钠 |
| 收稿时间： | 1989-07-21 |
119Sn AND 23Na NMR STUDY ON THE INTERACTION BETWEEN Na4Sn9 AND COMPLEXES |
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| Wang Xin,Yang Xujie,Lu Lude,Song Qize,Wang Wenze and Gu Weihong. 119Sn AND 23Na NMR STUDY ON THE INTERACTION BETWEEN Na4Sn9 AND COMPLEXES[J]. Chinese Journal of Inorganic Chemistry, 1992, 8(1): 62-64 |
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| Authors: | Wang Xin Yang Xujie Lu Lude Song Qize Wang Wenze Gu Weihong |
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| Affiliation: | Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014,Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014,Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014,Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014,Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014 and Modern Chemistry Laboratory, East China Institute of Technology, Nanjing 210014 |
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| Abstract: | In the present work the interaction between the Na4Sn9 Zintl alloy extract in en and complexes M(acacen)(M = Cu,Ni) as well as Ln(fod)3(Ln= Pr,Yb,Eu) has been investigated by multinuclear magnetic resonance. The interpretation of the findings is discussed in terms of the NMR theory of paramagnetic ions and in relation to the magnetic properties of the complexes. It is concluded that the chemical shifts of Sn94- arise predominantly from pseudo-contact interaction and the change in volume susceptibility, while for Na+, only the effect of susceptibility is dominant. |
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| Keywords: | Zintliö n complex pseudo-contact |
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