Excess molar enthalpies of the ternary mixtures: methyl tert-butyl ether + 3-methylpentane + (n-decane or n-dodecane) at 298.15 K |
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Authors: | Zhaohui Wang Benjamin C-Y Lu |
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Institution: | Department of Chemical Engineering, University of Ottawa, Ottawa, Ont., Canada K1N 6N5 |
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Abstract: | Excess molar enthalpies, measured at 298.15 K in a flow microcalorimeter, are reported for the two ternary mixtures formed by mixing either methyl tert-butyl ether with binary mixtures of 3-methylpentane and either n-decane or n-dodecane. Smooth representations of the ternary results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. It is found that the Liebermann and Fried model also provided good representation of the ternary results, using only the physical properties of the components and their binary mixtures. |
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Keywords: | Methyl tert-butyl ether 3-Methylpentane n-Decane n-Dodecane Excess molar enthalpy Ternary systems Liebermann–Fried model |
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