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Regulating ambient pressure approach to graphitic carbon nitride towards dispersive layers and rich pyridinic nitrogen
Affiliation:1. Institute for Advanced Ceramics, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, China;2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, China;1. State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education, Beijing Engineering Research Center of Environmental Material for Water Purification, Beijing University of Chemical Technology, Beijing 100029, China;2. Department of Chemistry, Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM, Fudan University, Shanghai 200433, China
Abstract:An ambient pressure-induced calcination process was proposed to prepare g-C_3 N_4 with different structures.The porcelain boat with designed porosity is used to control the ambient pressure to change the diffusion behavior of the reaction molecules,thereby controlling the layer structure and rich pyridinic N content of g-C_3 N_4,thus renders superior lithium storage performance.
Keywords:Ambient pressure  Porosity  Spreading behavior  Carbon nitride  Lithium-ion battery
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