Taming heterogeneous rhenium catalysis for the production of biomass-derived chemicals |
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| Affiliation: | 1. IRCELYON, Univ Lyon, Université Claude Bernard Lyon 1, CNRS, UMR 5256, 2 avenue Albert Einstein, F-69626, Villeurbanne, France;2. Institut FCBA, InTechFibres, F-38044 Grenoble, France;1. Department of Applied Chemistry, School of Engineering, Tohoku University, 6-6-07, Aoba, Aramaki, Aoba-ku, Sendai 980-8579, Japan;2. Central Research & Development Laboratory, Showa Shell Sekiyu K.K., 4052-2 Nakatsu, Aikawa-cho, Aikoh-gun, Kanagawa-ken, Japan |
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| Abstract: | Rhenium is one of important components for heterogeneous catalysts,which has been recently used for the catalytic reactions related to the production of biomass-derived chemicals such as deoxydehydration of vicinal OH groups,C-O hydrogenolysis,and hydrogenation of carboxylic acids,and so on.Suitable oxidation state of Re as a catalytic active species is strongly dependent on the catalytic reactions.The control of the oxidation state of Re species on the catalysts is crucial on the catalyst development. |
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| Keywords: | Rhenium Oxidation state Deoxydehydration Hydrogenolysis Hydrogenation |
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