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Ultrathin MnO2 nanosheets grown on hollow carbon spheres with enhanced capacitive performance
Institution:1. Materials Science and Engineering Research Center, Guangxi University of Science and Technology, Liuzhou 545000, China;2. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, State Key Lab of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China
Abstract:Ultrathin MnO2 nanosheets grown on the surface of hollow carbon spheres (MnO2/HCSs) were fabricated by the redox reaction between carbon spheres with KMnO4 in aqueous solution. Due to the porous structure and large amounts of active sites, MnO2/HCSs exhibit excellent capacitive performance with 227.5 F g−1 at 1 A g−1. After 5000 cycles, the capacity retention of MnO2/HCSs remains 96%, indicating its good cycling stability. These results demonstrate that MnO2/HCSs are promising supercapacitor electrode material and this work provide a facile method for growth of ultrathin MnO2 nanosheets on carbon substrate.
Keywords:Hollow carbon spheres  Supercapacitor
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