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Ramanspektroskopische Untersuchungen an festem Vanadiumoxidtrichlorid VOCl3 |
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| Authors: | A. Feza Demiray and Wolfgang Brockner |
| Affiliation: | (1) School of Earth and Environment, University of Leeds, Leeds, LS2 9JT, UK;(2) Department of Earth and Environmental Sciences, Ludwig-Maximilians Universit?t, 80333 M?nchen, Germany;(3) Department of Mineralogy, University of Geneva, Rue des Mara?chers 13, 1205 Geneva, Switzerland |
| Abstract: | A high resolution Raman spectrum of polycrystalline VOCl3 at –196 °C has been recorded. Besides the chlorine isotope splitting a further splitting of 3 of the 6 fundamentals has been observed. The number of the Raman lines in the  4 and 6 region and the intensity ratios in the 2 region will be explained by a factor group splitting of 2 VOCl3 molecules in the unit cell. |
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