Synthesis of the enantiomer of the structure assigned to the natural product nobilisitine A |
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Authors: | Schwartz Brett D Jones Matthew T Banwell Martin G Cade Ian A |
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Affiliation: | Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra ACT 0200, Australia. |
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Abstract: | The synthesis of the enantiomer of the structure, 1, assigned to the natural product nobilisitine A has been accomplished using the enantiomerically pure cis-1,2-dihydrocatechol 4 as starting material. The (1)H and (13)C NMR spectral data derived from compound ent-1 do not match those reported for the natural product, thus suggesting its structure has been incorrectly assigned. |
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