Cp*IrCl2]2-catalyzed indirect functionalization of alcohols: novel strategies for the synthesis of substituted indoles |
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| Authors: | Whitney Simon Grigg Ronald Derrick Andrew Keep Ann |
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| Institution: | Molecular, Innovation, Diversity and Automated Synthesis Centre, Department of Chemistry, University of Leeds, Leeds LS2 9JT, United Kingdom. |
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| Abstract: | We report novel iridium(III)-catalyzed reactions that afford substituted indoles via the indirect functionalization of alcohols via C-3 selective alkylation of indoles with alcohols and a one-pot cascade strategy from amino- or nitro-phenyl ethyl alcohols, which incorporates oxidative cyclization and C-3 alkylation. |
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