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Interaction studies between photochromic spiropyrans and transition metal cations: the curious case of copper
Authors:Natali Manuel  Giordani Silvia
Institution:Trinity College Dublin, School of Chemistry, College Green, Dublin, 2, Ireland.
Abstract:A series of four spiropyrans bearing different substituents on the indolic nitrogen were synthesized and their capability of binding mono and bivalent transition metal cations in solution was assessed via UV-visible absorption spectroscopy. All the compounds responded selectively to the presence of Cu(ii) ions producing intense absorption bands in the visible region of their spectra. Bidimensional (1)H-NMR and MALDI-TOF MS spectroscopies revealed the formation of SP dimers mediated by Cu(ii). This is the first example of cross-coupling mediated by copper(ii) in mild conditions causing the symmetric dimerization of spiropyran dyes.
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