| αH,αH,ωH-全氟烷氧丙基甲基二氯硅烷的制备和水解反应研究 |
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| 引用本文： | 娄峡,刘振华,卓仁禧. αH,αH,ωH-全氟烷氧丙基甲基二氯硅烷的制备和水解反应研究[J]. 高分子学报, 1987, 0(3): 226-229 |
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| 作者姓名： | 娄峡 刘振华 卓仁禧 |
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| 作者单位： | 武汉大学化学系 武汉(娄峡，刘振华)，武汉大学化学系 武汉(卓仁禧) |
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| 摘 要： | <正>我们以十六烷基三甲基澳化按为相转移催化剂,将四氟乙烯调聚醇与氛丙烯在氢氧化钠存在下反应,制得三种
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| 关 键 词： | 硅氢化 烯丙基氟代烷基醚 氟代烷氧丙基硅烷 氟代烷氧丙基环四硅氧烷 |
| 收稿时间： | 1986-01-31 |
STUDY ON THE PREPARATION AND HYDROLYSIS OF αH, αH, ωH-PERFLUOROALKOXYPROPYLME-THYLDICHLOROSILANE |
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| LOU Xia,LIU Zhen-hua,ZHUO Ren-xi. STUDY ON THE PREPARATION AND HYDROLYSIS OF αH, αH, ωH-PERFLUOROALKOXYPROPYLME-THYLDICHLOROSILANE[J]. Acta Polymerica Sinica, 1987, 0(3): 226-229 |
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| Authors: | LOU Xia LIU Zhen-hua ZHUO Ren-xi |
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| Affiliation: | Department of Chemistry; Wuhan University; Wuhan |
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| Abstract: | In this paper, we wish to report the preparation of three new αH, αH, ωH-perfluoroalko-xypropylmethyldichlorosilanes, e.g. 1H, 1H, 3H- perfluoropropoxypropylmethyldichlorosilane, 1H, 1H, 5H-perfluoropentoxypropylmethyldichlorosilane and 1H, 1H, 7H-perfluoroheptoxypro-pylmethyldichlorosilane. Upon hydrolysis or cohydrolysis of these fluoroalkoxypropylmethyldt-chlorosilane monomers with dimethyldichlorosilane, seven αH, αH, ωH-perfluoroalkoxypropyl-methylcyclotetrasiloxanes were obtained. The chemical structures of these new organosilicon compounds were confirmed. |
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| Keywords: | Hydrosilylation Allyl fluoroalkyl ether Fluoroalkoxyproplsilane Fluo-roalkoxypropylcyclotetrasiloxane |
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