| Crystal Structure of 1，5－Bis（Ts），1，5－diaza－13－crown－4（Ts＝p－methylphenylsulfonyl） |
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| 作者姓名： | Mao Jiang-Gao |
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| 作者单位： | Mao Jiang-Gao (Fujian Institute of Research on the Structure of Matter，Academia Sinica，Fuzhou 350002) Jin Zhong-Sheng;Piao Rong-He(Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022) |
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| 摘 要： | ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ１，５－Ｂｉｓ（Ｔｓ），１，５－ｄｉａｚａ－１３－ｃｒｏｗｎ－４（Ｔｓ＝ｐ－ｍｅｔｈｙｌｐｈｅｎｙｌｓｕｌｆｏｎｙｌ）ＭａｏＪｉａｎｇ－Ｇａｏ（ＦｕｊｉａｎＩｎｓｔｉｔｕｔｅｏｆＲｅｓｅａｒｃｈｏｎｔｈｅＳｔｒｕｃ...
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Crystal Structure of 1,5-Bis(Ts),1,5-diaza-13-crown-4(Ts=p-methylphenylsulfonyl) |
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| Mao Jiang-Gao.Crystal Structure of 1,5-Bis(Ts),1,5-diaza-13-crown-4(Ts=p-methylphenylsulfonyl)[J].Chinese Journal of Structural Chemistry,1994(5). |
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| Authors: | Mao Jiang-Gao |
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| Abstract: | Crystals of the title compound were obtained when it reacted with lanthanum(Ⅲ) chloride in DMF/MeOH mixed solvent.C23H32O6N2S2 (Mr=496.7),triclinic,P1,with a=10.133(2),b=14.054(2),c=9.194(0),α=102.52(1),β=102.22(1),γ=96.70(1)°,V= 1230.9(3) 3;Z=2;Dc=1.34 gcm13;F (000)=528;μ=2.6 cm-1(MoKα).The final R and Rω are 0.043 and 0.047,respectively for 1880 reflections with Ⅰ>3σ(Ⅰ).The mean distances of C-N ,C-O,S-C and S-O are 1.478,1.417,1.762 and 1.434,respectively. |
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| Keywords: | crystal structure crown ether synthesis |
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