Raman-spectrum investigation of the conformations of cis-and trans-1,3-dimethylcyclohexanols |
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| Authors: | M. I. Batuev A. A. Akhrem A. V. Kamernitskii A. D. Matveeva |
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| Affiliation: | (1) Institute of Mineral Fuels, USSR;(2) N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Summary When configurations are named with respect to the actually largest substituents, the preferred conformation for the compound (I) in the liquid phase is trans-1e3a, and for compound (II) in the liquid phase cis-1e3e with equatorial hydrogen-bonded hydroxyls; when this nomenclature, based on the actually largest substituents is used, the Auwers-Sktta rule is not reversed for the compounds (I) and (II) in the liquid state. |
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