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Covalently anchored sulfonic acid on silica gel (SiO2-R-SO3H) as an efficient and reusable heterogeneous catalyst for the one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions
引用本文:Gholam Hossein Mahdavinia,Mohammad A.Bigdeli,Yaser Saeidi Hayeniaz. Covalently anchored sulfonic acid on silica gel (SiO2-R-SO3H) as an efficient and reusable heterogeneous catalyst for the one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions[J]. 中国化学快报, 2009, 20(5): 539-541. DOI: 10.1016/j.cclet.2008.12.026
作者姓名:Gholam Hossein Mahdavinia  Mohammad A.Bigdeli  Yaser Saeidi Hayeniaz
作者单位:a Department of Chemistry, Islamic Azad University-Marvdasht Branch, Marvdasht, Iran;b Faculty of Chemistry, Tarbiat Moalem University, 49 Mofateh Street, Tehran, Iran
摘    要:

关 键 词:非均相催化剂  一锅法合成  无溶剂条件  二氧化硅  可重复使用  硅胶  共价固定  有效率

Covalently anchored sulfonic acid on silica gel(SiO_2-R-SO_3H)as an efficient and reusable heterogeneous catalyst for the one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions
Gholam Hossein Mahdaviniaa,Mohammad A.Bigdeli,Yaser Saeidi Hayeniazb a. Covalently anchored sulfonic acid on silica gel(SiO_2-R-SO_3H)as an efficient and reusable heterogeneous catalyst for the one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions[J]. Chinese Chemical Letters, 2009, 20(5): 539-541. DOI: 10.1016/j.cclet.2008.12.026
Authors:Gholam Hossein Mahdaviniaa  Mohammad A.Bigdeli  Yaser Saeidi Hayeniazb a
Affiliation:a Department of Chemistry, Islamic Azad University-Marvdasht Branch, Marvdasht, Iran;b Faculty of Chemistry, Tarbiat Moalem University, 49 Mofateh Street, Tehran, Iran
Abstract:A highly efficient one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions catalyzed by sulfonic acid covalently anchored onto the surface of silica gel is reported.All types of aldehydes,including aromatic,unsaturated,and heterocyclic,are used.The silica gel/sulfonic acid catalyst (SiO2-R-SO3H) is completely heterogeneous and can be recycled.
Keywords:1,8-Dioxooctahydroxanthenes  Heterogeneous catalysis  SiO2-R-SO3H  Reusable
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