Copolymerization and homopolymerization reactions in systems containing electron-donor monomer,electron-acceptor monomer,and lewis acid |
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| Authors: | Witold Kuran Stanis&#x;aw Pasynkiewicz Zbigniew Florja&#x;czyk Danuta &#x;yszkowska |
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| Institution: | Witold Kuran,Stanisław Pasynkiewicz,Zbigniew Florjańczyk,Danuta Łyszkowska |
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| Abstract: | Investigations of the copolymerization of acrylonitrile, methacrylonitrile, methyl acrylate, methyl methacrylate, acrylic acid, acryloyl chloride, methyl vinyl ketone, and acrolein with styrene, and of acrylonitrile with acenaphthylene and 1,3-cyclopentadiene in the presence of Lewis acids as catalysts have been carried out. It was found that the free-radical alternating copolymerization and ionic copolymerization or homopolymerization reactions can proceed in these systems. The yield of the competitive free-radical and ionic reactions was related to the type of monomers and strength of the Lewis acid. The mechanism of the catalytic effect of Lewis acids in the reactions studied is discussed. |
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