Thermal [1, 3] benzoyl migration in 1-(α-benzoyloxyarylideneamino)-1,2,3-triazoles. Part II |
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Authors: | W. Kehrbach N. E. Alexandrou |
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Abstract: | 1-(α-Benzoyloxyarylideneamino)-4, 5-dirnethyl-1,2,3-triazoles (V) were prepared by reacting the sodium salt of substituted 1-benzoylamino-4, 5-dimethyl-1,2,3-triazoles (IV) with benzoyl chloride at ?50°. The uncatalyzed thermal isomerization of isoimides V to the corresponding imides VI was studied kinetically and the reaction mechanism is discussed. |
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