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Time-resolved spectroscopy of solvated electrons
Affiliation:1. Department of Physics, School of Science, Dalian Maritime University, Dalian 116026, Liaoning, China;2. State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;3. Department of Chemical Physics, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China;4. Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams, Chinese Ministry of Education, School of Physics, Dalian University of Technology, Dalian 116024, China;5. Key Laboratory of Chemical Lasers, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;6. University of Chinese Academy of Sciences, Beijing 100049, China;7. Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China;8. Hefei National Laboratory, Hefei 230088, China;1. School of Opto-Electronic Engineering, Zaozhuang University, Zaozhuang 277160, China;2. Weifang University of Science and Technology, Shouguang 262700, China;3. School of Artificial Intelligence, Zaozhuang University, Zaozhuang 277160, China
Abstract:The theory of time-dependent transient spectra of solvated electrons is developed. It is shown that the evolution of the spectral line centre reproduces the time dependence of the classical correlation function of the random process of electronic energy level fluctuations. The results of this investigation are compared with experiment.
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