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Diffusive transient recombination kinetics of interacting molecules
Affiliation:1. Electronic Engineering Department, Universitat Politècnica de Catalunya, Jordi Girona 1–3, Barcelona 08034, Spain;2. Centre de Recerca en Nanoenginyeria (CrNE), Pascual Vila 15, Barcelona 08028, Spain;1. School of Photovoltaic and Renewable Energy Engineering, The University of New South Wales, Sydney NSW2052, Australia;2. Research School of Engineering, College of Engineering and Computer Science, The Australian National University, Canberra ACT2601, Australia;1. College of Mechanical Engineering, Guangxi University, 100, Daxue Dong Road, Nanning 530004, China;2. Institute of Applied Mechanics, National Taiwan University, 1 Sec. 4, Roosevelt Road, Taipei 106, Taiwan;3. Research Center of Applied Sciences, Academia Sinica, Taipei 115, Taiwan
Abstract:A simple analytical approach to diffusive geminate recombination kinetics of interacting molecules is considered. The expressions obtained describe accurately the transient time dependence and show that the kinetics is exponential at short times and follows a power law at long times. This approach is applied to some time-resolved experiments on ion-radical pair recombination.
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