Synthesis and characterization of a tetrazolate-bridged coordination framework encapsulating D2h-symmetric cyclic (H2O)4 cluster arrays |
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| Authors: | Tao Jun Ma Zhi-Jie Huang Rong-Bin Zheng Lan-Sun |
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| Institution: | Department of Chemistry and State Key Laboratory for Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, P. R. China. taojun@jingxian.xmu.edu.cn |
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| Abstract: | Reaction of 5,5'-(1,4-phenylene)bis(1H-tetrazole), which was prepared in two steps, with cadmium nitrate in DMF produced a three-dimensional framework with one-dimensional channels (35% void volume), in which unprecedented hydrogen-bond-supported D(2)(h)() tetrameric cyclic water clusters ranked. |
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