Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4 |
| |
Authors: | NIU Chang-rong JIANG Hua WU Cheng-tai LUO Bao-sheng |
| |
Institution: | 1. Department of Chemistry, Wuhan University 430072;
2. Center of Instrumental Analysis, Wuhan University, Wuhan 430072 |
| |
Abstract: | The crystal structure of the title compound C14H21ONS2 was determined by means of X-ray diffraction method.Its crystallog raphic data are as follows:Mr=283.46,it is a monoclinic crystal system,the space group P21/n,a=1.273 7(3)nm,b=1.510 9(5)nm,c=0.798 0(6)nm,=107.17(3)°,V=1.467 4 nm3,Z=4,Dc=1.283 g·cm-3,(MoK)=3.370 cm-1,F(000)=608,R1=0.079,Rw=0.076 for 1.689 observed reflections with I≥6(I).Both the phenyl and hetero cyclic rings in the title compound are distorted to form a conjugate system. |
| |
Keywords: | Crystal structure Free ligand Mixed-donor macromolecular ligand |
本文献已被 CNKI 等数据库收录! |
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |
|