On the dynamics of excitations in disordered systems |
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Authors: | Shaul Mukamel |
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Affiliation: | (1) Department of Chemistry, University of Rochester, 14627 Rochester, New York |
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Abstract: | A new, time-local (TL) reduced equation of motion for the probability distribution of excitations in a disordered system is developed. ToO(k2) the TL equation results in a Gaussian spatial probability distribution, i.e, P(r, t) = [(2)1/2]–dexp(-r2/22), where = (t) is a correlation length, andr = ¦r¦. The corresponding distribution derived from the Hahn-Zwanzig (HZ) equation is more complicated and assumes the asymptotic (r ) form: P(r, s)(sd)–1exp(–r/) · (r/)(1-d)/2 where = (s),d is the space dimensionality, ands is the Laplace transform variable conjugate tot. The HZ distribution generalizes the scaling form suggested by Alexanderet al. ford= 1. In the Markov limit (t)t, (s)1/s, and the two distributions are identical (ordinary diffusion). |
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Keywords: | Disordered system diffusion master equations non-Markovian dynamics |
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