Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20 |
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| Institution: | 1. Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, 230026 Hefei, China;2. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation;1. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;2. Department of Biology, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;3. Federal Research Centre ‘Fundamentals of Biotechnology’ of the Russian Academy of Sciences, 119071 Moscow, Russian Federation;1. M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, 119454 Moscow, Russian Federation;2. Peptide Chemistry Research Center, K. N. Toosi University of Technology, P.O. Box 15875-4416, Tehran, Iran;3. Medical Biology Research Center, Kermanshah University of Medical Sciences, P. O. Box 67155-1616, Kermanshah, Iran;4. St. Petersburg State University, 199034 St. Petersburg, Russian Federation;5. Immanuel Kant Baltic Federal University, 236016 Kaliningrad, Russian Federation;1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033 Irkutsk, Russian Federation;2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation |
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| Abstract: | Chlorofullerenes C86(16)Cl16 and C86(17)Cl18,20 were prepared by chlorination of Cs-C86(16) and C2-C86(17), respectively, with VCl4 at 320–340 °C. An X-ray crystallo- graphic study with the use of synchrotron radiation revealed the chlorination patterns which show certain similarity due to only small differences between isomeric C86 cages. |
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| Keywords: | higher fullerenes chlorination IPR isomers structure elucidation |
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