Group 4 metal silylidenes and germylidenes: towards the silicon and germanium variations of olefin metathesis |
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| Affiliation: | 1. A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;2. N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation;1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. National Research University Higher School of Economics (HSE University), 101000 Moscow, Russian Federation;3. G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russian Federation;1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620990 Ekaterinburg, Russian Federation;2. Perm National Research Polytechnic University, 614990 Perm, Russian Federation |
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| Abstract: | The current progress in the field of the stable Schrock-type silylidenes and germylidenes of the group 4 metals, along with their prospective use in the development of the silicon or germanium variations of olefin metathesis, is briefly overviewed in this focus article. |
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| Keywords: | germanium germylidenes metathesis Schrock complex silicon silylidenes |
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