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The M5 photoelectron line of Ag metal measured in coincidence with the M5–N45N45 Auger-electron spectral line
Institution:1. Faculty of Environmental Earth Science, Hokkaido University, N10W5, Kita-ku, Sapporo 060-0810, Japan;2. Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo 060-0810, Japan;3. Laboratory of Chemistry, Hokkaido University of Education Sapporo, Ainosato 5-3-1, Kita-ku, Sapporo 002-8502, Japan;1. Department of Physical Chemistry and Applied Thermodynamics, Institute of Fine Chemistry and Nanochemistry, University of Cordoba, Campus Rabanales, Ed. Marie Curie 2ª Planta, E-14014 Córdoba, Spain;2. Department of Organic Chemistry, Faculty of Sciences, University of Málaga, 29071 Málaga, Spain
Abstract:The M5 (3d5/2) photoelectron line of Ag metal was measured in coincidence with the M5–N45N45 (1G or 3F) Auger-electron line by Auger-photoelectron coincidence spectroscopy (APECS). The M5 photoelectron line of Ag metal measured in coincidence with either the 1G or the 3F Auger-electron line is unshifted, within the accuracy of the experiment. As the theory M. Ohno, J. Electron Spectrosc. Relat. Phenom. 124 (2002) 53] predicts, the energy shift and asymmetrical narrowing of the coincidence photoelectron line compared to the singles one is much smaller than that in Cu metal.
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