Studies on mixture of ionic liquid EMIGaCl4 and EMIC |
| |
| Institution: | 1. Center for Fuel Cell Innovation, School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China;2. Research Institute of Huazhong University of Science and Technology in Shenzhen, Shenzhen, Guangdong 518000, China;1. LSRE-Laboratory of Separation and Reaction Engineering, Associate Laboratory LSRE/LCM, Department of Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s/n, Porto 4200-465, Portugal;2. PLAPIQUI, Universidad Nacional del Sur-CONICET, Camino La Carrindanga Km 7, 8000 Bahía Blanca, Argentina;1. Department of Electrical and Computer Engineering, Cleveland State University, Cleveland, OH 44115, USA;2. The Applied Bioengineering Program, Cleveland State University, Cleveland, OH 44115, USA |
| |
| Abstract: | The densities of ionic liquid compound EMIGaCl4 and its mixtures with EMIC were measured by pycnometry in the temperature range from 308.15 to 343.15 K. The values of apparent molar volume of the mixture, partial molar volume and apparent molar expansibilities of EMIC were determined. Both Raman scattering and ab initio calculations were performed. All results show that GaCl4− is sole anion in ionic liquid compound EMIGaCl4 and is predominant one in the mixture composed of EMIC and ionic liquid compound EMIGaCl4. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
