| INVESTIGATION ON SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CLUSTER COMPLEX,[(MoS_4)Fe(MoS_4O)] [(C_4H_9)_4N]_3 |
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| 作者姓名： | 徐丽娟 王凤山 吕品喆 樊玉国 |
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| 作者单位： | Department of Chemistry，Jilin University，Changchun，Department of Chemistry，Jilin University，Changchun，Institute of Theoretical Chemistry，Jilin University，Changchun，Institute of Theoretical Chemistry，Jilin University，Changchun |
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| 摘 要： | In this paper, we report a new Mo-Fe-S cluster complex containing an oxygen ligand. Itwas synthesized by the reaction of (NH_4)_2 MoS_4, FeCl_3 in the solution of sodium glycol. The chemical formula of the crystal, (MoS_4) Fe (MoS_4O)] (C_4H_9)_4N]_3, was characterized byX-ray. This complex was determined by IR, UV/Vis and Mossbauer spectra as well. The re-suits from Mossbauer spectra of the complex show an isomer shift, δ_m = 0.2263mm/s and aquadrupole splitting, E_q = 0.4527mm/s. The complex has some activity for the reduetion of aectylene to ethylene in the presenceof KBH_4.
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