| 铽-聚N-乙烯基乙酰胺体系中镧钆掺杂稀土配合物谱学研究 |
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| 引用本文： | 孙勇,陈明清,陆天虹,Mitsuru Akashi,黄晓华.铽-聚N-乙烯基乙酰胺体系中镧钆掺杂稀土配合物谱学研究[J].光谱学与光谱分析,2006,26(4):698-702. |
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| 作者姓名： | 孙勇 陈明清 陆天虹 Mitsuru Akashi 黄晓华 |
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| 作者单位： | 江南大学化学与材料工程学院,江苏,无锡,214036;南京师范大学化学与环境科学学院,江苏,南京,210097;中国科学院长春应用化学研究所,吉林,长春,130022;大阪大学工学部分子化学系,日本,吹田市,565-0871;江南大学化学与材料工程学院,江苏,无锡,214036;南京师范大学化学与环境科学学院,江苏,南京,210097 |
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| 基金项目： | 国家高技术研究发展计划(863计划)
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国家计委稀土专项基金
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江苏省高技术研究发展计划项目 |
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| 摘 要： | 在乙醇溶液中合成了掺杂镧和钆的铽-聚N-乙烯基乙酰胺(PNVA)的掺杂稀土配合物, 并通过红外光谱、紫外光谱、 XPS光电子能谱和荧光光谱研究了该配合物的光谱性质. 结果表明: 掺杂稀土配合物中的稀土离子都与高分子配体PNVA产生配位作用. 配合物的最佳激发波长为303 nm;在此波长激发下, 配合物发出较强铽的特征荧光, 说明非荧光稀土离子(La3 和Gd3 )对Tb3 离子的发光有显著的增强作用, 而对Tb3 的发射峰位影响不大.
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| 关 键 词： | 稀土 配合物 荧光光谱 |
| 文章编号： | 1000-0593（2006）04-0698-05 |
| 收稿时间： | 2004-11-30 |
| 修稿时间： | 2005-03-26 |
Study on Spectroscopic Properties of Rare Earth Complexes with Poly(N-Vinylacetamide) |
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| SUN Yong,CHEN Ming-qing,LU Tian-hong,Mitsuru Akashi,HUANG Xiao-hua.Study on Spectroscopic Properties of Rare Earth Complexes with Poly(N-Vinylacetamide)[J].Spectroscopy and Spectral Analysis,2006,26(4):698-702. |
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| Authors: | SUN Yong CHEN Ming-qing LU Tian-hong Mitsuru Akashi HUANG Xiao-hua |
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| Institution: | 1. School of Chemistry and Materials, Southern Yangtze University, Wuxi 214036, China; 2. College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210097, China; 3. Changehun Institute of Applied Chemistry, Chinese Academy of Sciences, Changehun 130022, China; 4. Department of Molecular Chemistry, Graduate School of Engineering, Osaka University, 2 1 Yamada-oka, Suita 565-0871, Japan |
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| Abstract: | Terbium-lanthanum(or gadolinium)-poly(N-vinylacetamide) complexes were synthesized and characterized by UV-Vis absorption spectroscopy,FTIR,XPS and fluorescence spectroscopy.The results of UV-Vis,FTIR and XPS suggested that(terbium) and lanthanum(or gadolinium) ions were bonded to amide group of PNVA polymer.Fluorescence experiment indicated that the characteristic emission intensity of terbium ion was greatly increased and possibly sensitized by lanthanum ion(or gadolinium).Moreover,the wavelengths of terbium characteristic emissions were changed slightly.Also the characteristic emission(intensity) of terbium ion doped with lanthanum ion was better than that with gadolinium ion. |
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| Keywords: | Rare earth Complexes Fluorescence spectroscopy |
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