| 超临界二氧化碳介质中钯催化的一些交叉偶联反应的研究 |
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| 引用本文： | 张涛,冯秀娟,王春霞,包明. 超临界二氧化碳介质中钯催化的一些交叉偶联反应的研究[J]. 有机化学, 2007, 27(12): 1463-1472 |
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| 作者姓名： | 张涛 冯秀娟 王春霞 包明 |
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| 作者单位： | 大连理工大学精细化工国家重点实验室,大连,116012 |
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| 基金项目： | 国家自然科学基金(No.20603005)资助项目 |
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| 摘 要： | 构建新的C—C键, 在有机合成中占有非常重要的地位; 超临界二氧化碳, 作为环境友好的有机反应介质, 已引起人们的广泛关注. 综述了近年来超临界二氧化碳介质中钯催化的C—C键形成反应的研究进展, 包括Heck, Suzuki, Stille和Sonogashira反应等.
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| 关 键 词： | 超临界二氧化碳 钯催化 C—C键形成反应 |
| 收稿时间： | 2006-12-28 |
| 修稿时间： | 2007-04-16 |
Cross-Coupling Reactions Catalyzed by Palladium in Supercritical Carbon Dioxide |
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| ZHANG,Tao,FENG,Xiu-Juan,WANG,Chun-Xia,BAO,Ming. Cross-Coupling Reactions Catalyzed by Palladium in Supercritical Carbon Dioxide[J]. Chinese Journal of Organic Chemistry, 2007, 27(12): 1463-1472 |
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| Authors: | ZHANG Tao FENG Xiu-Juan WANG Chun-Xia BAO Ming |
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| Affiliation: | (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012) |
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| Abstract: | The construction of new carbon-carbon bond is very important in organic synthesis. The super-critical carbon dioxide has attracted considerable attention because it can be used as an environmentally be-nign medium for organic reactions. In this paper, palladium catalyzed cross-coupling reactions to form new carbon-carbon bond including Heck reaction, Suzuki reaction, Stille reaction as well as Sonogashira reac-tion, proceeded in supercritical carbon dioxide are reviewed. |
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| Keywords: | supercritical carbon dioxide palladium catalysis carbon-carbon bond formation |
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