Application of the energy gap law to the decay of charge transfer excited states,solvent effects |
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| Authors: | Jonathan V. Caspar B.Patrick Sullivan Edward M. Kober Thomas J. Meyer |
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| Affiliation: | Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina 27514, USA |
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| Abstract: | Values of non-radiative decay rate constants (knr) and emission energies (Ecm) have been obtained for Os(Phen3)2+ in a series of solvents and the results are consistent with the energy gap law. For hydroxylic solvents like water or methanol related studies suggest the existence of strong, specific contributions to the vibrational trapping energy of the solvent. |
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