Dinitrogen: a selective probe for tri-coordinate Al "defect" sites on alumina |
| |
| Authors: | Wischert Raphael Copéret Christophe Delbecq Françoise Sautet Philippe |
| |
| Affiliation: | ETH Zürich, Department of Chemistry, Wolfgang-Pauli Strasse 10, CH-8093, Zürich, Switzerland. |
| |
| Abstract: | ![]()
Dinitrogen selectively binds to tri-coordinate Al(III) sites of the (110) termination of γ- and δ-alumina, the "defects" responsible for the low temperature dissociation of methane. Similar observations on η-Al(2)O(3) and extra framework aluminium of microporous aluminosilicates also suggest the presence of Al(III) sites on these materials. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
