Anion-directed assembly of a three-dimensional metal-organic rotaxane framework |
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| Authors: | Gong Han-Yuan Rambo Brett M Cho Won Lynch Vincent M Oh Moonhyun Sessler Jonathan L |
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| Institution: | Department of Chemistry & Biochemistry, University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0165, USA. |
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| Abstract: | A three-dimensional extended, metal-organic rotaxane framework (MORF) that incorporates encircled "struts" has been synthesized through a one-pot self-assembly process involving a macrocyclic tetraimidazolium "molecular box", naphthalene dicaboxylate dianion, and Zn(II) cations. The present system represents progress towards controlling the features of three-dimensional metal-organic frameworks. |
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