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New layered cobalt oxyfluoride, Sr2CoO3F |
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| Authors: | Tsujimoto Yoshihiro Li Jun J Yamaura Kazunari Matsushita Yoshitaka Katsuya Yoshio Tanaka Masahiko Shirako Yuichi Akaogi Masaki Takayama-Muromachi Eiji |
| Institution: | International Center for Young Scientists (ICYS), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan. TSUJIMOTO.Yoshihiro@nims.go.jp |
| Abstract: | The first Ruddlesden-Popper type layered cobalt oxyfluoride, Sr(2)CoO(3)F, has been synthesized under a pressure of 6 GPa at 1700 °C and shown to adopt a K(2)NiF(4)-type structure with distorted square pyramidal coordination around Co and with O/F disorder at the apical sites. |
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