Trigonal-prismatic CuII6-pyrazolato cages: structural and electrochemical study, evidence of charge delocalisation |
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| Authors: | Mezei Gellert Rivera-Carrillo Marlyn Raptis Raphael G |
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| Institution: | Department of Chemistry, University of Puerto Rico, San Juan, PR 00931-3346. |
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| Abstract: | Hexanuclear CuII-complexes of formula PPNCu6(micro3-O)2(micro-4-Rpz)6(micro-4-R'-3,5-Ph2pz)3] have been structurally characterized and the effect of pyrazole substituents on their two consecutive one-electron oxidation processes, leading to (possibly delocalised) mixed-valent products, has been probed by cyclic voltammetry. |
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