| Abstract: | By small-angle x-ray scattering, a systematic investigation was performed of the long spacing of poly(ethylene terephthalate) (PET) crystallized in a liquid environment. The results indicated that the measured long spacings were temperature dependent and apparently relatively insensitive to liquid type under the conditions studied. The kinetic nucleation model of polymer crystallization was found to adequately explain this dependence. The differences in the long spacings between thermal and liquid-induced crystallization were in part rationalized in terms of the suspected supercoolings involved in the respective processes. Calculation of the spherulite growth rates for liquid-induced crystallization was made on the basis of the kinetic nucleation model and the classic theory of polymer–diluent crystallization. The results were shown to agree with inferential experimental observations of these growth rates and to elucidate the physics underlying liquid–induced crystallization. Finally, use of this growth rate theory in conjunction with a previous model for overall crystallization kinetics was shown to adequately describe and predict the diffusion-limited kinetics observed experimentally for most liquid-induced crystallization situations. |
