| 核磁共振研究二茂铁硒铂配合物构象交换热焓 |
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| 引用本文： | 阎江丽,毛希安,沈联芳.核磁共振研究二茂铁硒铂配合物构象交换热焓[J].物理化学学报,1997,13(9):853-856. |
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| 作者姓名： | 阎江丽 毛希安 沈联芳 |
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| 作者单位： | State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics,Wuhan Institute of Physics,The Chinese Academy of Sciences,Wuhan 430071,People's Republic of China |
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| 摘 要： |
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| 关 键 词： | 构象交换热 核磁共振 二氯化铂的二茂铁硒醚配合物 |
| 收稿时间： | 1996-12-06 |
| 修稿时间： | 1997-05-29 |
Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with 1H NMR |
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| Yan Jiang-Li,Mao Xi-An,Shen Lian-Fang.Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with 1H NMR[J].Acta Physico-Chimica Sinica,1997,13(9):853-856. |
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| Authors: | Yan Jiang-Li Mao Xi-An Shen Lian-Fang |
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| Institution: | State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics,Wuhan Institute of Physics,The Chinese Academy of Sciences,Wuhan 430071,People's Republic of China |
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| Abstract: | The intramolecular conformational exchange thermodynamics of cis-PtCl1,1'bis(undecenylseleno)ferrocene](B11SeFcPt) in CDCl3 solution was studied by one dimensional proton NMR． The chemical equilibrium constants were obtained directly from the integration of the 1H NMR spectra and the enthalpy as a function of temperature for the conformational exchange of B11SeFcPt was calculated from the equilibrium constant. |
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| Keywords: | Conformational exchange enthalpy 1H NMR' ') 1H NMR" target="_blank">">1H NMR 2' ') Selenoferrocene complex of PtCl2" target="_blank">">Selenoferrocene complex of PtCl2 |
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