| N-苯基亚氨基二乙酸镍二维网状配合物的合成及结构表征(英) |
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| 引用本文： | 郝志峰,张耀方,陈耀文,余坚,余林.N-苯基亚氨基二乙酸镍二维网状配合物的合成及结构表征(英)[J].无机化学学报,2005,21(4):573-577. |
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| 作者姓名： | 郝志峰 张耀方 陈耀文 余坚 余林 |
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| 作者单位： | 1. 广东工业大学轻工化工学院,广州,510006
2. 汕头大学中心实验室,汕头,510063 |
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| 基金项目： | 广东省自然科学基金资助项目(No.994397)，广东省自然科学基金团队资助项目(No.04205301)。 |
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| 摘 要： | A new nickel(Ⅱ) coordination compound Ni(L2-)(2,2′-bipy)(H2O)]·2H2O (H2L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl2·6H2O in the mixed solvent of water and ethanol (V∶V=1∶1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P21 /c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=2.643 5(5) nm, β=91.01(1)°, V=2.080 2(4) nm3, Z=4, F(000)=992, Dc=1.520 Mg·m-3, R1=0.027 0 and wR2=0.067 5. In the complex, nickel (Ⅱ) atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC: 244926.
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| 关 键 词： | N-苯基亚氨基二乙酸 氢键 晶体结构 镍(Ⅱ)配合物 |
| 收稿时间： | 2004/8/18 0:00:00 |
| 修稿时间： | 2004/12/2 0:00:00 |
Synthesis and Structure of 2D Nickel(Ⅱ) Coordination Compound with Phenyl-Iminodiacetic Acid |
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| HAO Zhi-Feng,ZHANG Yao-Fang,CHEN Yao-Wen,YU Jian and YU Lin.Synthesis and Structure of 2D Nickel(Ⅱ) Coordination Compound with Phenyl-Iminodiacetic Acid[J].Chinese Journal of Inorganic Chemistry,2005,21(4):573-577. |
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| Authors: | HAO Zhi-Feng ZHANG Yao-Fang CHEN Yao-Wen YU Jian and YU Lin |
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| Institution: | Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006,Central Laboratory, Shantou University, Shantou 515063,Central Laboratory, Shantou University, Shantou 515063,Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 and Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 |
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| Abstract: | A new nickel(Ⅱ) coordination compound Ni(L2-)(2,2'-bipy)(H2O)]· 2H2O (H2L=phenyliminodiacetic acid)water and ethanol (V:V=1:1). The complex was characterized by elemental analysis, IR spectra, and X-ray crys-tallography analysis. The crystal is monoclinic, space group P21/c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=In the complex, nickel (Ⅱ) atom is coordinated with a distorted octahedral geometry and extensive hydrogen bondslink the complexes into a 2D network structure. CCDC: 244926. |
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| Keywords: | phenyl-iminodiacetic acid hydrogen bond crystal structure Ni complex |
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